As mentioned earlier, it is because they have one of the most complete freshwater collections in the world. An example: Most people that visit public aquarums could be mislead into thinking South American freshwater pretty much only consists of two Amazonian habitats: Flooded forests and blackwater rivers. Sure these are important habitats, but they're only a fairly small percentage of the Amazon, let alone all South American freshwater habitats. If you visit Berlin you'll find both these, but you'll also find South American aquariums aimed at the the Guiana Shield, Orinoco, Xingu River (representing a clearwater river), Pantanal (an unusual wetland that mainly is associated with the Paraguay basin, but in periods of flood also is connected to the upper Madeira/Tapajós basins), Paraguay River (itself part of the Rio de la Plata basin, which I suspect relatively few have heard about despite it having an average discharge similar to the Mississippi+Danube combined), etc. In other words, a much more complete representation of South American freshwater. It's the same with freshwater of other continents, although their coverage of the Nearctic is mediocre (however aquatic fauna from this region overall is quite similar to the Palearctic). The reptile/amphibian sections in the same building are also quite good and do include aquatic highlights such as gharial.