Is it a single polar bear? Does it have glass viewing (glass breaking risk?) Is it closed for night?
From my mind:
- changing meal times every day (also reduces pacing before feeding time)
- medical training - the bear is taught to stand still, present feet, open mouth etc. for a veterinary inspection and rewarded with food.
- any toy which is good for big dog should work
- pieces of meat, skin, bones to chew
- ice treats made from filling a bucket with water and some vegetables and freezing it into a block.
- a platform for the bear to climb and look over the area around
- any big bright plastic thing which floats - like water canister or traffic cone
Generally, enrichment to be enriching MUST be varied. Giving few toys and leaving them forever will make bear bored again. Zoos often have a monthly plan, with new enrichment every day.
Optimal would be leaving the bear outside for night, or at least bedding in the night quarters.
See also:
https://www.aza.org/ uploadedfiles/ animal_care_and_management/ husbandry, _health, _and_welfare/ husbandry_and_animal_care/ polarbearcaremanual.pdf
There was an article which I cannot find now, and it evaluated what enrichment actually works best with bears. It should be on the internet. It looks eg. that toys are enrichment which is most often given, but least interesting for bears.